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Hazardous Waste - Disposal

Final disposal of hazardous waste


Hazardous wastes undergo different treatments in order to stabilize and dispose of them.


Recycling


Many HWs can be recycled into new products. Examples might include lead-acid batteries or electronic circuit boards where the heavy metals can be recovered and used in new products.Another example is the ash generated by coal-fired power plants; these plants produced two types of these residues: fly and bottom ash. Fly ash particles have a low density, are very fine, and are removed by air pollution control devices. On the other side, bottom ash is a dense, dark, gravely substance that remains on the bottom of combustion chambers. After these types of ashes go though the proper treatment, they could bind to other pollutants and convert them into easier-to- dispose solids, or they could be used as pavement filling. Such treatments reduce the level of threat of harmful chemicals, like fly and bottom ash, while also recycling the safe product and helping the environment.


Portland cement


Another commonly used treatment is cement based solidification and stabilization. Cement is used because it can treat a range of hazardous wastes by improving physical characteristics and decreasing the toxicity and transmission of contaminants. The cement produced is categorized into 5 different divisions, depending on its strength and components. This process of converting sludge into cement might include the addition of pH adjustment agents, phosphates, or sulfur reagents to reduce the settling or curing time, increase the compressive strength, or reduce the leach ability of contaminants.


Neutralization


Some HW can be processed so that the hazardous component of the waste is eliminated: making it a non-hazardous waste. An example of this might include a corrosive acid that is neutralized with a basic substance so that it is no-longer corrosive. (see acid-base reactions.)Another mean to neutralize some of the waste is pH adjustment. pH is an important factor on the leaching activity of the hazardous waste. By adjusting the pH of some toxic materials, we are reducing the leaching ability of the waste.


Incineration, destruction and waste-to-energy


A HW may be "destroyed" for example by incinerating it at a high temperature. Flammable wastes can sometimes be burned as energy sources. For example many cement kilns burn HWs like used oils or solvents. Today incineration treatments not only reduce the amount of hazardous waste. They also generate energy throughout the gases released in the process. It is known that this particular waste treatment releases toxic gases produced by the combustion of byproduct or other materials and this can affect the environment. However, current technology has developed more efficient incinerator units that control these emissions to a point that this treatment is considered a more beneficial option. There are different types of incinerators and they vary depending on the characteristics of the waste. Starved air incineration is another method used to treat hazardous wastes. Just like in common incineration, burning occurs, however controlling the amount of oxygen allowed proves to be significant to reduce the amount of harmful bi products produced. Starved Air Incineration is an improvement of the traditional incinerators in terms of air pollution. Using this technology it is possible to control the combustion rate of the waste and therefore reduce the air pollutants produce in the process.

 

Hazardous waste landfill (sequestering, isolation, etc.)


A HW may be sequestered in a HW landfill or permanent disposal facility. "In terms of hazardous waste, a landfill is defined as a disposal facility or part of a facility where hazardous waste is placed or on land and which is not a pile, a land treatment facility, a surface impoundment, an underground injection well, a salt dome formation, a salt bed formation, an underground mine, a cave, or a corrective action management unit (40 CFR 260.10)."[6][7]


Pyrolysis


Some hazardous waste types may be eliminated using pyrolisis in an ultra high temperature electrical arc, in inert conditions to avoid combustion. This treatment method may be preferable to high temperature incineration in some circumstances such as in the destruction of concentrated organic waste types, including PCBs, pesticides and other persistent organic pollutants.


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